Reviews on Baeyer-Villiger Catalyzed Oxidation Research

Lei Ziqiang, Zhang Qinghua, Luo Jujie
(College of Chemistry and Chemical Engineering, Northwest Normal University, LanZhou 730070)

Abstract Baeyer-Villiger oxidation isａfrequently used synthetic method for conversion of carbonyl compounds into corresponding ester or lactones. The research works of catalyzed Baeyer-Villiger oxidation in the latest ten years have been reviewed in this article. Transition metal complexes catalysis system, organic tin catalysis system as well as organic/inorganic compound catalysis system was introduced respectively, the merits and shortbacks of a variety of catalytic oxidation systems were also discussed in detail.
Key words Baeyer-Villiger reaction, Catalyzed oxidation, Ketone

催化氧化Baeyer-Villiger反应的研究进展

雷自强 张青花 罗居杰
(西北师范大学化学化工学院 兰州 730070)

摘要 Baeyer-Villiger反应是将环酮或酮氧化成内酯或酯的一类重要反应。本文综述了近10年来用化学方法催化氧化Baeyer-Villiger反应的研究新进展，分别介绍了过渡金属复合物催化体系、有机锡化合物催化体系、有机/无机化合物催化体系, 并对各种催化体系的优缺点及其研究发展的趋势进行了较为详细的分析。
关键词 Baeyer-Villiger反应 催化氧化 酮

雷自强 男，46岁，教授，主要从事催化氧化、高分子材料等研究工作。
国家自然科学基金资助项目(20474052)
2003-11-24收稿，2004-04-28接受

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