Selective Oxidation of Alcohols with Aqueous Hydrogen Peroxide

Zhao Gongda, Lü Ying, Xi Zuwei, Gao Shuang*
(Dalian Institute of Chemical Physics，Chinese Academy of Sciences，Dalian 116023)

Abstract The recent advances in selective oxidation of alcohols with aqueous hydrogen peroxide were reviewed. The oxidation mechanism for H2O2-metal-catalyst was induced. The green oxidation methods in fine chemistry were discussed in both heterogeneous catalysis and homogeneous catalysis. The direction in industry development of oxidation of alcohols with aqueous hydrogen peroxide was described.
Key words Catalytic oxidation, Alcohols, H2O2

　

H2O2为氧源的醇类选择性氧化

赵公大 吕迎 奚祖威 高爽*
(中国科学院大连化学物理研究所 大连 116023)

摘 要 综述了以H2O2作为氧化剂的醇类催化氧化的研究进展。归纳了H2O2-金属催化剂体系的氧化机制，从多相催化与匀相催化两方面讨论了在精细有机合成中有广泛应用的绿色氧化方法。指出了醇类的H2O2催化氧化体系的工业发展方向。
关键词 催化氧化 醇 H2O2

赵公大 27岁，硕士，从事匀相催化氧化研究。*联系人，E-mail: gaos@dicp.ac.cn
2003-11-16收稿，2004-02-25接受

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