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Advances in Mesoporous Silica Morphologies Dang Wenxiu, Han Shuhua, Hou Wanguo*, Xu Jun, Yan Xin Abstract A
variety of morphologies of mesoporous silica, such as sphere, rod, fiber, helicoid, hollow
tubule and other radial patterns, can be synthesized by using surfactants as templates in
either alkaline or acid solution. The formation of particular morphology depends on the
experimental conditions of synthesis, including surfactant, cosolvent, precursor,
counterions, acidity, temperature and so on. Several morphogenesis mechanisms, such as
supramolecule origami mechanism, geometric matching mechanism, singularity-fluctuation
mechanism and defect effect mechanism, are proposed in recent years. The latest advances
in the particular morphology of silica-based mesoporous materials are summarized in this
paper. 介孔氧化硅材料形貌的研究进展 党文修 韩书华 侯万国*
许
军 闫
欣 摘要 综述了介孔氧化硅材料形貌的最新研究进展，归纳总结了球形、棒状、纤维、螺旋、中空管和放射外形等形貌的介孔氧化硅的合成方法，着重阐述了超分子折叠机理、几何匹配机理、特性区扰动机理以及缺陷作用机理等形貌形成机理。 党文修
男，35岁，硕士，现从事介孔材料的形态控制研究。*联系人
E-mail:wghou@sdu.edu.cn |