Synthesis, Properties and Applications of Dendronized Polymers Xu Youyong, Gao Chao*, Wang Shoubo, Yan Deyue (College of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240) Abstract Dendronized polymers are one sort of dendritic polymers with dendrons as side groups and linear polymer as core. Because of their unique architecture, structure, properties and potential applications, dendronized polymers have been drawing more and more attention. This review briefly introduced the subclasses and synthesis strategies of dendritic polymers, and focused on the development, structure, synthesis, characterization, properties and applications of dendronized polymers, and then the prospect of the cylindrical macromolecules was anticipated. Key words Dendronized polymer, Dendrimer, Dendritic, Hyperbranched, Nanometer 柱状树枝化聚合物的合成、性质及应用 徐友勇 高 超* 王寿柏 颜德岳 (上海交通大学化学化工学院 上海 200240) 摘要 柱状树枝化聚合物是一种具有树状构造的以树枝单元为侧基、线型聚合物为核的柱状纳米级大分子。由于其独特的结构、形貌及性能，该类聚合物的研究正受到越来越多的关注。本文简介了具有树枝状构造的聚合物的类型及合成策略，重点评述了柱状树枝化聚合物的结构特点、表征方法、合成路线、性质及应用，并展望了其发展趋势和方向。 关键词 树枝化聚合物 树形大分子 树状 超支化 纳米 徐友勇 男，24岁，硕士生，现从事超支化及柱状聚合物的合成和功能化的研究工作。 *联系人 国家自然科学基金重点资助项目(50233030) 2003-03-28收稿，2003-06-09修回 (PDF全文下载c04019)