Advances in the Study on Hydrogen Transfer to a,w-Diarylalkanes

Ni Zhonghai, Zhang Lifang, Wang Junling, Zong Zhimin, Wei Xianyong*
(School of Chemical Engineering, CUMT, Xuzhou 221008)

Abatract As the most relevant coal model compounds,a,w-diarylalkanes (DAAs) were extensively investigated for studying mechanism of coal liquefaction. The advances in the study on hydrogen transfer to DAAs are reviewed in the paper. The effects of catalyst, hydrogen donor solvent and molecular structures of DAAs on hydrogen transfer to DAAs were mainly discussed. The emphasis is laid on basic research of coal liquefaction to realize high added-value utilization of coal.
Key words Hydrogen transfer, Model compound, Coal liquefaction

　

二芳基烷烃的氢转移反应

倪中海 张丽芳 王俊玲 宗志敏 魏贤勇*
(中国矿业大学化学工程学院 徐州 221008)

摘要 作为煤相关模型化合物，二芳基烷烃(DAAs)已被广泛用于研究煤液化机理。本文综述了近年来涉及DAAs的氢转移反应研究的进展，着重讨论了催化剂、供氢溶剂和DAAs的分子结构对氢转移反应的影响，指出应大力加强煤液化基础研究，以实现煤的高附加值利用。
关键词 氢转移 模型化合物 煤液化

倪中海 男，25岁，硕士生，现从事煤及其相关模型化合物氢转移机理的研究。* 联系人
国家自然科学基金资助项目(29676045和20076051)
2001-12-16收稿，2002-07-12修回

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