Calculation of Solubility Parameter for Liquids

Hu Fuxin
(Chemistry and Chemical Engineering College, Xinyang Normal University, Xinyang Henan 464000)

Abstract On the basis of the definition for solubility parameter, the correlation equation is used for vaporization enthalpy in conjunction with critical property and eccentric factor. Solubility parameters of 50 kinds of solvents have been calculated. The results of calculation for the solubility parameters werecompared with those in the reference literature, the average relative error is 1.98%.
Key words Liquid, Solubility parameter, Vaporization enthalpy, Eccentric factor, Critical property

液体溶解度参数的计算

胡付欣
(信阳师范学院化学化工学院 河南信阳 464000)

摘要 根据液体溶解度参数的定义，用蒸发焓与液体临界性质和偏心因子的关联方程，计算得到了50种液体的溶解度参数。计算结果与文献值比较，平均相对误差为1.98%。
关键词 液体 溶解度参数 蒸发焓 偏心因子 临界性质

胡付欣 男，43岁，副教授，主要从事溶液热力学研究。
2002-01-14收稿，2002-05-15修回