Dispersion Polymerization

Zhang Kai, Zeng Min, Lei Yi, Jiang Luxia
(Dep. of Polym. Mat. & Eng., Sichuan Univ., Chengdu 610065)

Abstract Dispersion polymerization is a new polymerization method. This method involves monomer, stabilizer and initiator dissolved in the reaction media to polymerize with the formation of insoluble polymer dispersed in the reaction media by the stabilizer. Dispersion polymerization has been applied in many fields, such as coating, bioengineering, medicine, chemistry industry etc. In this paper, the two major problems of the polymerization process, including the stabilizing effec of the polymer dispersion and reaction mechanism are reviewed.
Key words Dispersion polymerization, Stabilization effect, Reaction mechanism

 

分散聚合反应

张 凯  曾 敏  雷 毅  江璐霞*
(四川大学高分子材料科学与工程系 成都 610065)

摘要 分散聚合反应是一种新的聚合方法,反应开始前,单体、引发剂和分散剂均溶解在介质中,随着反应的进行,当聚合物链达到临界值时便会从介质中分离出来,并借助于分散剂稳定地悬浮在介质中。分散聚合方法已被应用于许多领域,如涂料工业、生物工程、医学、化学工业等。本文对分散聚合反应的两个主要问题,即分散体系的稳定作用和反应机理的研究状况进行了概述。
关键词 分散聚合 稳定作用 反应机理


张凯 男,28岁,硕士,主要从事高分子材料合成及改性研究,E-mail:zhangkaiw@elong.com *联系人
2002-01-28收稿,2002-04-03修回

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