Chiral Discrimination on Cellulose and Cellulose Derivatives

Weng Wen, Zeng Qingle^#, Shen Jianfang, Huang Jianhui
(Department of Chemistry,Zhangzhou Teachers College, Zhangzhou,363000
^#Chengdu Institute of Organic Chemistry，Academic Sinica, Chengdu,610041)

Abstract Cellulose and cellulose derivatives, particularly cellulose tribenzoates and tri (phenylcarbamates), have been widely used on chiral resolution by chromatography. Their applications on chiral shift reagents by NMR, chiral enrichment through membranes, chiral catalysis have also been drawn the great attention. The mechanism of chiral inducement of this compound is complicated because of the existence of supramolecular structure.
Key words Cellulose, Cellulose derivatives, Chiral discrimination

纤维素及其衍生物的手性诱导效应

摘要 纤维素及其衍生物，特别是纤维素三苯甲酸酯、三苯基氨基甲酸酯系列在色谱手性拆分已得到较广泛的应用。纤维素衍生物在核磁共振手性位移试剂、手性膜分离富集、手性催化等领域的应用也引起了人们的注意。因为超分子结构的存在，此类化合物的手性诱导机制比较复杂，与多种因素有关。
关键词 纤维素 纤维素衍生物 手性识别

翁文 男，28岁，硕士，讲师，从事催化化学的教学与科学工作。   E-mail:wwxiaoyaoyou@163.net
福建省高校重点科技项目基金资助(JA99210)
2001-10-21收稿，2002-03-06修回