The New Development in Calixarene Radicals and Their Inclusion Chemistry

Li Yong, Wang Qi, Wu Guoshi
(Department of Chemistry, Tsinghua University, Beijing 100084)

Abstract Calixarenes and their derivatives have received considerable attention because of their peculiar molecular architecture and outstanding properties in host-guest chemistry. Now a new field of calixarenes concerned with radical chemistry is rapidly developing. It is expected that studies in detail should be helpful to exploring the complexation and inclusion theory as well as to designing calixarene-based sensing agents, organic magnetic materials etc. The advance in such a crossing field is reviewed.
Key words Calixarenes, Host-guest interaction, Free radicals, Electron spin resonance

 

自由基杯芳烃化合物及其包合物

王 琪  李 勇  吴国是
(清华大学化学系 北京 100084)

摘要 杯芳烃及其衍生物由于特殊的分子结构和出众的主体分子性质,在超分子领域得到广泛应用。近几年,自由基的引入给杯芳烃化学带来了新的活力。本文对这一交叉领域的最新进展作一介绍。
关键词 杯芳烃 主客体化学 自由基 电子自旋共振


李 勇 男,40,副教授,博士,主要从事顺磁共振的研究。   E-mail: liy@chem.tsinghua.edu.cn
2001-07-23收稿,2001-10-26修回

(PDF全文下载c02030)