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A Novel Chemenzyme——Heterobimetallic Multifunctional Chiral Catalyst Wu Shuxin, Ma Zhi, Qin Yongning Abstract Heterobimetallic
multifunctional chiral catalysts and their applications in asymmetric catalyst are
described. Higher yield and enantiomeric excess can be obtained using this kind of novel
catalysts because of the cooperativity among the two different metals and the chiral
template in catalyst. It has been shown that heterobimetallic multifunctional chiral
catalysts have broad prospects in pharmaceutical and organic synthesis.
一种新型化学酶——异双金属多功能手性催化剂 吴树新 马 智 秦永宁* 摘要
介绍了异双金属多功能手性催化剂的结构、催化性能、应用情况及最新研究动向。这种新颖的催化剂借助两种金属和手性模板之间的协同效应,能获取更高的化学产率和光学收率,在制药、有机合成中有广泛的应用前景。 吴树新 男,32岁,工业催化专业博士生。 *联系人 E-mail:wushuxin1@eyou.com 2001-06-30收稿,2001-08-31修回 |