A Novel Chemenzyme——Heterobimetallic Multifunctional Chiral Catalyst

Wu Shuxin,  Ma Zhi,  Qin Yongning
School of Chemical Engineering and TechnologyTianjin University, Tianjin 300072

Abstract Heterobimetallic multifunctional chiral catalysts and their applications in asymmetric catalyst are described. Higher yield and enantiomeric excess can be obtained using this kind of novel catalysts because of the cooperativity among the two different metals and the chiral template in catalyst. It has been shown that heterobimetallic multifunctional chiral catalysts have broad prospects in pharmaceutical and organic synthesis.
Key words Heterobimetallic, Multifunctional, Chiral catalyst, Cooperativity

 

一种新型化学酶——异双金属多功能手性催化剂

吴树新  马 智  秦永宁*
(天津大学化工学院  天津  300072)

摘要 介绍了异双金属多功能手性催化剂的结构、催化性能、应用情况及最新研究动向。这种新颖的催化剂借助两种金属和手性模板之间的协同效应,能获取更高的化学产率和光学收率,在制药、有机合成中有广泛的应用前景。
关键词 异双金属 多功能 手性催化剂 协同效应


吴树新 男,32岁,工业催化专业博士生。 *联系人 E-mail:wushuxin1@eyou.com
2001-06-30收稿,2001-08-31修回

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