Progress On Synthesis of [60]Fullerene Dimer
Xu Juhua, Luo Hongyuan
(College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082)
Abstract More and more people have been interested in [60]fullerene
dimers because of the potential application of [60]fullerene dimers in areas such as
artificial photosynthesis, novel molecular electronic devices and supramolecular
chemistry. The synthetic manners of [60]fullerene dimers were summarized according to 30
literatures in recent years, and were concluded three types: (1) addition reaction; (2)
coupling reaction; (3) hydrogen bonding between two molecules.
Key words [60]Fullerene, Synthesis, Addition reaction, Coupling reaction,
Hydrogen bonding
[60]富勒烯二聚体的合成研究进展
徐菊华 罗红元
(湖南大学化学化工学院 湖南长沙 410082)
摘要 [60]富勒烯二聚体化合物,由于在人工光合成、新的分子电子器件和超分子化学中具有潜在的应用,引起人们的兴趣。本文综述了近几年国内外对该类化合物的合成情况,其合成方法可归纳为三类:一是利用加成反应;二是利用分子间的偶合反应,三是利用分子间的氢健作用。
关键词 [60]富勒烯 合成 加成反应 偶合反应 氢键
徐菊华
男,博士,副教授,主要从事富勒烯化学和有机合成。
2001-06-26收稿,2001-07-26修回