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Studies on Mechanism for Synthesis of Octylglucoside Catalyzed by Zinc Chloride Chen Kan, Zhang Jianhua, Chen Zenai, Lu Yang Abstract The mechanism to synthesize the octyl-D-glucopyranosidel catalyzed by zinc chloride is suggested. The factors that affect the constitution of products are discussed. The experiment results show that the substituent in C-2 of D-glucose is the major factor for the ratio of a-isomer to b-isomer.Key words Mechanism of the reaction, Octylglucopyranoside
氯化锌催化合成正辛基葡萄糖苷反应机理研究 陈侃 张建华 陈泽乃 陆阳* 摘要 报道了氯化锌催化合成正辛基-D-吡喃葡萄糖苷反应机理的研究，考察了影响产物构型的因素。实验结果表明D-葡萄糖C-2取代基是影响产物a、b-异构体比例的重要因素。 陈侃 男，27岁，硕士，从事有机化学和药物化学的研究。
*联系人 E-mail: huaxue@shsmu.edu.cn |