Catalytic Hydrogenolysis of the Benzyl-type Alcohols Liu Xiaohui, Wang Xinhong, Lu Guanzhong (Research Institute of Industrial Catalysis, Eastchina University of Technology Shanghai 200237) Abstract The methods, catalysts and reaction mechanism of the hydrogenolysis of benzyl-type alcohols are reviewed. The contents consist of hydrogenolysis with H2, the effect of substitutents, solvents, aryl halides on the reaction; the catalytic transfer hydrogenolysis with hydrogen donors, hydrogen-donating abilites of various formate salts; and the application of the organic electrochemistry at hydrogenolysis of benzyl-type alcohols. Key words Benzyl-type alcohols, Hydrogenolysis, Catalyst, Mechanism 苄基型醇催化氢解反应 刘晓晖 王新宏 卢冠忠* (华东理工大学工业催化研究所 上海 200237) 摘要 简要介绍了苄基型醇催化氢解的方法、催化剂和催化反应的机理。内容包括了用分子氢催化氢解反应，取代基团、溶剂及卤代芳烃等因素对直接催化氢解反应的影响；用非分子氢的催化转移氢解反应，非分子氢氢源给氢能力的强弱；有机电化学在醇氢解方面的应用等。 关键词 苄基型醇 氢解 催化剂 反应机理 刘晓晖 女，27岁，研究生，现从事丙烯环氧化和 a，a-二甲基苯甲醇氢解的研究工作。*联系人，E-mail:gzhlu@ecust.edu.cn (PDF全文下载c02041)