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| 碳化钙作为固体炔源的绿色合成策略及 C-C 键构建研究进展 |
| Research Progress on Green Synthesis Strategies and C-C Bond Construction Using Calcium Carbide as a Solid Acetylene Surrogate |
| 投稿时间：2026-04-10 修订日期：2026-05-06 |
| DOI： |
| 中文关键词: 碳化钙 炔源 绿色 有机合成 |
| 英文关键词:calcium carbide, alkyne source, green, organic synthesis |
| 基金项目:2026年宁夏自然科学基金项目（2026AAC031225）；国家自然科学基金项目（Grant no. U24A20485），2025年度宁夏自治区青年科技托举人才培养项目， |
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| 中文摘要: |
| 碳化钙作为一种来源广泛、价格低廉的工业原料，在传统精细化工合成中通常需先转化为气态乙炔，但该过程存在易燃易爆风险、操作复杂、成本较高及应用范围受限等问题。随着绿色发展理念的深入，以碳化钙为固态炔源直接参与有机反应已成为该领域的研究热点。碳化钙在有机合成中展现出优异的反应活性，可用于构建多种有机化合物。基于此，本文综述了近年来以碳化钙为炔源直接合成有机化合物的研究进展，重点探讨其在乙烯基与乙炔基化合物构建中的应用及相关反应机理，并对该领域的未来发展方向进行展望。 |
| 英文摘要: |
| Calcium carbide is a readily available and low-cost industrial raw material. In traditional fine chemical synthesis, it is typically converted into gaseous acetylene, which is flammable and explosive, involves complex operations, incurs high costs, and has limited application scope. With the growing emphasis on green chemistry, the direct use of calcium carbide as a solid alkyne source in organic reactions has become a research hotspot. Calcium carbide exhibits excellent reactivity in organic synthesis, enabling the construction of various organic compounds. On this basis, this paper reviews recent advances in the direct synthesis of organic compounds using calcium carbide as the alkyne source, with a focus on its applications in the construction of vinyl and ethynyl compounds, along with the corresponding reaction mechanisms. Future development trends in this field are also discussed. |
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