| 李超,王波,石心雨.化学通报,2026,89(4):402-415,423. |
| 碳化钙：作为绿色廉价稳定的乙炔源合成有机化合物 |
| Calcium Carbide: A green, inexpensive, and stable source of acetylene for synthesizing organic compound |
| 投稿时间：2025-11-10 修订日期：2026-02-05 |
| DOI： |
| 中文关键词: 碳化钙 乙炔 绿色化学 有机合成 |
| 英文关键词:Calcium carbide, Acetylene, Green chemistry, Organic synthesis |
| 基金项目:陕西省科技厅自然科学基础研究计划项目（2019JQ-776），陕西省教育厅专项科研计划项目（19JK0104） |
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| 中文摘要: |
| 碳化钙作为一种来源广泛、绿色、经济的固态炔源，在工业领域和有机合成化学中发挥着重要作用。与乙炔气相比，碳化钙性质稳定，具有许多优点：无易燃易爆风险，使用时易于获取和使用，碳化钙的合成也不依赖石油和天然气。因此，本文阐述了碳化钙作为乙炔源的反应特性与优势，系统综述了碳化钙作为乙炔源近年来在构建各类有机分子中的应用和最新研究进展，并且对反应类型和反应机理进行了介绍。通过与其他炔源的对比和对相关文献的分析和整合，探讨了碳化钙作为乙炔源在绿色化学和有机合成中的新化学反应和高价值应用和未来发展趋势。 |
| 英文摘要: |
| As a widely available, environmentally friendly, and economical solid acetylene source, calcium carbide plays a significant role in industrial applications and organic synthesis chemistry. Compared to acetylene gas, calcium carbide offers numerous advantages due to its stable properties: it poses no flammable or explosive risks, is readily accessible and easy to use, and its synthesis does not rely on petroleum or natural gas. Therefore, this paper elucidates the reaction characteristics and advantages of alcium carbide as an acetylene source, it systematically reviews recent applications and research advances in utilizing calcium carbide for constructing diverse organic molecules, while introducing reaction types and mechanisms. Through comparisons with other acetylene sources and analysis of relevant literature, it explores novel chemical reactions, high-value applications, and future development trends for calcium carbide as an acetylene source in green chemistry and organic synthesis. |
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