| 沈钰涵,熊芸,刘生鹏,闫策,王翎谕,吴晓宇,孙海辉,代志凯.化学通报,2026,89(3):254-262. |
| 金属有机框架材料作为环境友好型催化剂研究进展 |
| Research Progress of Metal-Orgnic Framework as Environmentally Friendly Catalysts |
| 投稿时间：2025-09-23 修订日期：2025-11-11 |
| DOI： |
| 中文关键词: 环境友好型催化剂 金属有机框架材料 MOF基催化剂 催化氧化/还原 酶催化 污染物降解 |
| 英文关键词:environmentally friendly catalyst MOF materials MOF based catalyst electro-chemical catalysis catalytic oxidation/reduction enzymatic catalysis degradation of pollutant substance |
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| 摘要点击次数: 371 |
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| 中文摘要: |
| 环境友好型催化剂作为绿色化工的重要组成部分之一，寻找对环境友好的绿色催化剂成为发展绿色化工的一项重要任务。金属有机框架 (MOF)基催化剂具有高比表面积、孔径/孔容可精确调控、高密度分散的活性位点和优异的可循环性的催化特性，在过去几十年里取得了巨大的进展。本文主要综述了金属有机框架材料在污染物催化氧化降解、选择性催化氧化/还原、催化成环加成和酶催化的研究进展，并在此基础上对MOFs作环境友好型催化剂存在稳定性不足、规模化制备困难及电子传递效率低等问题提出了多维度的解决方案，以推动MOF在环境友好型催化中的工业化应用。 |
| 英文摘要: |
| Environmentally friendly catalysts, as a crucial component of green chemistry, have become a significant focus in the development of sustainable chemical processes. Metal-organic framework (MOF)-based catalysts, characterized by their high specific surface area, precisely tunable pore size/volume, highly dispersed active sites, and excellent recyclability, have witnessed remarkable advancements over the past few decades. This paper provides a comprehensive review of recent advancements in the application of metal-organic frameworks (MOFs) for catalytic processes, including pollutant oxidation and degradation, selective catalytic oxidation/ reduction, catalytic cycloaddition, and enzymatic catalysis. Building upon this foundation, a multi-dimensional solution has been proposed to address the challenges associated with MOFs as environmentally friendly catalysts, including insufficient stability, difficulties in large-scale preparation, and low electron transfer efficiency, thereby facilitating the industrial application of MOFs in environmentally friendly catalysis. |
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